Methyl Chloroform Mixture for Precision Cleaning
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🧪 Methyl Chloroform Mixture for Precision Cleaning
🌐 HS Code Reference & Customs Clearance Guide | 2026 Latest Tariff Analysis | Professional Compliance Strategy
📌 I. Product Definition & Classification: What is "Methyl Chloroform"?
In international trade and chemical engineering, "Methyl Chloroform" typically refers to 1,1,1-Trichloroethane (1,1,1-TCA).
However, it is crucial to distinguish between the pure chemical substance and the mixture/formulation used for cleaning.
1. Pure 1,1,1-Trichloroethane (Industrial Grade):
A halogenated hydrocarbon solvent, historically used for degreasing and precision cleaning.
⚠️ Regulatory Status: Strictly regulated under the Montreal Protocol due to its ozone-depleting potential (ODP) and greenhouse gas effects. Production and import are heavily restricted or banned in many jurisdictions.
2. Methyl Chloroform Mixture for Precision Cleaning (Formulated Product):
A commercial mixture containing 1,1,1-TCA combined with other solvents (e.g., hydrofluoroethers, chlorinated fluorocarbons, or alcohols) to enhance cleaning efficiency and safety.
📌 Key Classification Rule:
- If the product is a mixture/formulation intended for a specific purpose (cleaning), it generally falls under HS Code 3824.
- If it is pure 1,1,1-TCA (>99%), it falls under HS Code 2903.⚠️ Critical Distinction:
- Pure Chemical → Chapter 29 (Organic Chemicals)
- Mixture/Formulation for Cleaning → Chapter 38 (Miscellaneous Chemical Products)
📦 II. HS Code Classification Details (2026 Latest Tariff Authority)
| HS Code | Product Description | Applicable Scenario | Key Criteria |
|---|---|---|---|
| 2903.39.90 | Halogenated derivatives of acyclic hydrocarbons: Other (Pure 1,1,1-Trichloroethane) | Pure chemical solvent, raw material | Purity >95%, no other active ingredients |
| 3824.72.00 | Pre-mixed paints, varnishes, enamel... (Wait, no) → 3824.99.99 (Other chemical products) → Actually, 3824.72 is for Paints. Let's correct. | 3824.99.99 or 3824.72? No. For solvents in mixtures: 3824.99.99 is often used if not specified elsewhere. However, 3824.72 is for paints. 3824.99.99 is a residual category. Better Code: 3824.72.00 is incorrect. 3824.99.99 is common for miscellaneous solvent mixtures. Let's check 3824.72: "Pre-mixed paints..." No. Let's check 3824.99: "Other chemical products...". Alternative: If the mixture is dominated by 1,1,1-TCA, some customs authorities may still classify under 2903.39.90 if the other components are negligible. Standard Practice: 3824.99.99 (Miscellaneous Chemical Products) for formulated cleaning mixtures. |
Formulated cleaning solution, contains additives |
| 3402.90.00 | Organic surface-active agents (including wetting agents, etc.) | If the mixture contains significant surfactants/emulsifiers | Acts as a surfactant formulation |
🔍 Key Reminder:
- Pure 1,1,1-TCA is classified under 2903.39.90.
- Formulated Mixture for cleaning is typically classified under 3824.99.99 (Miscellaneous Chemical Products) or 3402.90.00 if surfactants are key.
- DO NOT classify formulated mixtures as pure chemicals to avoid regulatory penalties.
💰 III. 2026 Latest Tariff Rate Details (Including Surtaxes, Policy Surcharges)
✅ Applicable Country: United States (US)
✅ Country of Origin: China (CN)
✅ Effective Date: November 10, 2025 (and subsequent imports)
🎯 1. 2903.39.90 —— Pure 1,1,1-Trichloroethane (Halogenated Derivative)
| Item | Content |
|---|---|
| Base Tariff | 5.6% (ad valorem) |
| USITC Surtax (Section 301) | +25% (Footnote 9903.02.01) |
| IEEPA Surtax | +10% (For Chinese/HK origin, from Nov 10, 2025) |
| Total Tariff | 40.6% |
| Tax Calculation | CIF Value × 40.6% |
| De Minimis Exemption | ❌ Not Eligible (deny_de_minimis) |
| Legal Basis Path | IEEPA:9903.01.25 → IEEPA:9903.01.24 → USITC:2903.39.90 → FOOTNOTE:9903.02.01 |
📌 Explanation:
- Pure 1,1,1-TCA is considered a controlled chemical. The 25% Section 301 surtax applies.
- The 10% IEEPA surtax adds to the burden.
- Total 40.6% is extremely high, making pure imports from China economically unviable for most cleaning applications.
🎯 2. 3824.99.99 —— Formulated Mixture for Precision Cleaning (Miscellaneous Chemical)
| Item | Content |
|---|---|
| Base Tariff | 5.8% (ad valorem) |
| USITC Surtax (Section 301) | +25% (Footnote 9903.02.01 applies to many chemical mixtures) |
| IEEPA Surtax | +10% (For Chinese/HK origin) |
| Total Tariff | 40.8% |
| Tax Calculation | CIF Value × 40.8% |
| De Minimis Exemption | ❌ Not Eligible (deny_de_minimis) |
| Legal Basis Path | IEEPA:9903.01.25 → IEEPA:9903.01.24 → USITC:3824.99.99 → FOOTNOTE:9903.02.01 |
📌 Note:
- Even if classified as a mixture, most chemical cleaning products from China are subject to Section 301 tariffs.
- The 10% IEEPA surtax is applied on top.
- Total 40.8% is comparable to pure chemicals.
🛠️ IV. Customs Clearance Practical Advice (Real-World Pitfall Avoidance Guide)
✅ 1. Document Checklist (Must-Have)
| Document | Required | Description |
|---|---|---|
| ✅ Safety Data Sheet (SDS) | ✔️ | Must comply with OSHA HazCom Standard (Section 1-16). Must list all components if mixture. |
| ✅ Product Specification Sheet | ✔️ | Define whether it is pure or mixture. Include CAS numbers for pure components. |
| ✅ Commercial Invoice | ✔️ | Clearly state "Formulated Cleaning Mixture" or "1,1,1-Trichloroethane, Pure". Do not use vague terms like "Solvent". |
| ✅ Certificate of Origin | ✔️ | If claiming FTZ or other exemptions (rare for China origin). |
| ✅ Import License (EPA/EEA) | ✔️ | CRITICAL: 1,1,1-TCA is regulated. May require EPA registration or import notification. |
| ✅ Filing 7501 | ✔️ | Entry Summary. Must declare accurate HTSUS code and duty calculation. |
✅ 2. Declaration Tips (Key Mantra)
🔥 "Pure vs. Mixture, SDS and CAS, EPA Rules, Don't Pass!"
| Scenario | Correct Declaration | Wrong Practice |
|---|---|---|
| Pure 1,1,1-TCA | HS: 2903.39.90, Name: "1,1,1-Trichloroethane, Pure" | Declaring as "Cleaning Solvent" → HS 3824 → Misclassification Penalty |
| Formulated Mixture | HS: 3824.99.99, Name: "Precision Cleaning Mixture" | Declaring as "Paint Remover" → HS 3824.72 → Incorrect Code |
| Non-Chinese Origin | Check for IEEPA Exemptions | Assuming all Chinese goods are taxed |
| Mixture with Unknown Components | Do Not Import without full disclosure | Hiding components → FDA/EPA Violation |
✅ 3. Special Handling
| Situation | Handling Advice |
|---|---|
| Ozone Depleting Substances (ODS) | 1,1,1-TCA is a Class I ODS. Import requires EPA Notification. Ensure you have the necessary permits. |
| Hazardous Materials (HazMat) | Classified as Flammable Liquid (Class 3) or Toxic (Class 6.1). Requires proper HazMat labeling and DOT compliance. |
| Small Samples | Even samples are subject to Section 301 tariffs. No de minimis exemption for chemicals. |
| Substitute Solvents | Consider HFE (Hydrofluoroethers) or D limonene alternatives. They may have lower tariffs or fewer regulatory hurdles. |
🌍 V. Global Major Market Clearance Comparison (2026 Latest)
| Country/Region | Recommended HS Code | Tariff Rate (China Origin) | Certification Requirements | Notes |
|---|---|---|---|---|
| 🇺🇸 USA | 2903.39.90 / 3824.99.99 |
40.6% - 40.8% | EPA Registration, OSHA SDS | Strict ODS regulations |
| 🇨🇳 China | 2903.39.90 |
5.0% - 6.0% | No Surtax | Production restricted |
| 🇪🇺 EU | 2903.39.90 |
5.3% + REACH Compliance | REACH Registration, CLP Labeling | 1,1,1-TCA is Banned in EU under REACH for most uses |
| 🇯🇵 Japan | 2903.39.90 |
3.0% - 4.0% | PRTR Law Notification | Strict environmental controls |
| 🇬🇧 UK | 2903.39.90 |
5.3% + UK REACH | UK REACH Registration | Post-Brexit, similar to EU |
📌 Conclusion:
- USA is the only major market allowing import with high tariffs.
- EU/UK have effectively banned 1,1,1-TCA for most cleaning uses. Do not attempt to export to EU.
- China has restricted production. Exporting from China may be difficult due to domestic controls.
📌 VI. Common Mistakes & Pitfall Guide (Blood-Teaching Lessons)
❌ Mistake 1: Declaring "Cleaning Mixture" as "Paint Striper"
👉 Consequence: Incorrect HS Code → Penalty + Audit
❌ Mistake 2: Ignoring EPA Regulations for 1,1,1-TCA
👉 Consequence: Seizure of Goods + Fines ($10,000+ per day)
❌ Mistake 3: Claiming "De Minimis" Exemption for Samples
👉 Consequence: Back Taxes + Interest (No exemption for chemicals)
❌ Mistake 4: Not Listing All Ingredients in SDS
👉 Consequence: Customs Hold + FDA/EPA Investigation
✅ Correct Action:
"Formulated Precision Cleaning Mixture, Contains 1,1,1-Trichloroethane (CAS 71-55-6), SDS Attached, EPA Notification Number: XXXXX"
🎯 VII. Conclusion: Professional Declaration, Time-Saving, Cost-Effective!
🎯 Remember the Mantra:
🔹 "Pure is 2903, Mixture is 3824, EPA Rules are Key, SDS Must Be Ready!"
🔹 "Tariff is 40%, HazMat Labeling is Mandatory, Banned in EU, Think Twice!"
📌 Tips:
- If your product is a mixture with low 1,1,1-TCA content, check if it can be classified under 3402.90.00 (Surfactants) to potentially avoid Section 301 tariffs.
- Consider alternative solvents like HFE-7100 or Cyrene which may have more favorable tariff treatments and regulatory status.
📣 Immediate Action:
📞 Contact a Chemical Customs Broker + Provide Full SDS + Apply for EPA Import Notification
🚀 Ensure your cleaning products pass customs smoothly, comply with EPA, and maximize profit!
✨ Professional Clearance Starts with Accurate Classification!
💼 Every Dollar Saved in Tariffs is Profit Gained!
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关于 HS 编码归类
协调制度(HS)是由世界海关组织(WCO)制定的国际贸易商品分类标准。全球 200 多个国家采用 HS 系统作为海关关税、贸易统计和进出口监管的基础。
每个 HS 编码遵循以下层级结构:
- 章(2 位)——商品大类(例如:第 84 章:机器和机械设备)
- 品目(4 位)——章内的更具体分类
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- 本国细分(8-10 位)——各国自行扩展的细分编码,如美国 HTSUS 10 位编码
正确的 HS 编码归类对于顺利通关、准确缴纳关税和遵守贸易法规至关重要。错误归类可能导致海关延误、多缴关税或罚款。
从CN进口到US时,适用的关税税率可能包括:
- 最惠国(MFN)税率——适用于 WTO 成员国的标准关税税率
- 普通税率——适用于无贸易协定国家
- 贸易救济关税——附加关税,如 301 条款(反倾销)、232 条款(国家安全)或反补贴税
本页内容仅供参考。如需正式归类,请咨询当地海关或持牌报关代理。