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Alkylbenzene Additive

CN → US
HS Code Tariff Rate Origin Destination Doc
3402311000 41.5% CN US Official Doc
3824401000 41.5% CN US Official Doc
3402319000 38.7% CN US Official Doc
3824994900 41.5% CN US Official Doc
3824994900 41.5% CN US Official Doc

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🧪 Alkylbenzene Additive (烷基苯增稠剂)


🌐 HS Code Reference & Customs Clearance Guide | 2026 Latest Tariff Analysis | Professional Clearance Strategy
📌 Part 1: Product Definition & Classification – What is “Alkylbenzene Additive”?

Alkylbenzene Additives are complex chemical substances primarily used as thickeners, surfactants, or industrial chemical additives. Depending on their specific chemical composition (e.g., linear alkylbenzene sulfonates, hydrocarbon mixtures, or functional surfactants), they may fall into different Harmonized System (HS) categories.

In international trade, these products are typically categorized into two main groups:

Surfactant-Based Products (Category 34):
Products classified as surface-active agents or preparations, featuring linear alkylbenzene sulfonic acid and its salts. These are often used in cleaning agents, detergents, or specialized chemical formulations.

Chemical Additives & Hydrocarbon Mixtures (Category 38):
Products classified as chemical industrial additives, aromatic substances, or hydrocarbon mixtures derived from petroleum, shale oil, or natural gas. These are used for thickening, stabilization, or other industrial chemical processes.

⚠️ Key Distinction Point:
- If the product is primarily a surface-active agent/surfactant with cleaning or wetting properties →归类 to 3402.31.10.00 or 3402.31.90.00
- If the product is a hydrocarbon mixture or general chemical additive without specific surfactant functions →归类 to 3824.40.10.00 or 3824.99.49.00


📦 Part 2: HS Code Classification Details (2026 Latest Tariff Authority Comparison)

HS Code Product Description Applicable Scenario Material Characteristic
3402.31.10.00 Alkylbenzene thickeners classified as surfactants/surfactant preparations; matches linear alkylbenzene sulfonate and its salt material features Specialized detergents, surface-active cleaning agents ✅ Surfactant/Anionic
3402.31.90.00 Alkylbenzene thickeners based on alkylbenzene chemical structure; functional chemicals within the scope of surfactants/cleaning agents General surfactant applications, functional chemical cleaners ✅ Surfactant/Functional
3824.40.10.00 Alkylbenzene thickeners classified as chemical industry additives; contains aromatic substances, matching chemical additive material features Industrial chemical mixtures, aromatic-based additives ✅ Chemical Additive
3824.99.49.00 Alkylbenzene mixtures classified as hydrocarbon substances; derived from petroleum, shale oil, or natural gas hydrocarbon mixtures Petroleum-derived hydrocarbon thickeners, industrial oil additives ✅ Hydrocarbon/Petroleum
3824.99.49.00 Alkylbenzene thickeners classified as hydrocarbon compounds; used in chemical industries General hydrocarbon-based industrial thickeners ✅ Hydrocarbon/Industrial

🔍 Key Reminder:
- All hydrocarbon-based or general chemical additive products without specific surfactant classification must be grouped into 3824.99.49.00 or 3824.40.10.00;
- If the product contains linear alkylbenzene sulfonates, it should be classified under 3402.31.10.00 (highest priority for surfactants).
- Misclassification risks: Declaring a hydrocarbon mixture as a surfactant (or vice versa) can lead to duty disputes, delays, or penalties.


💰 Part 3: 2026 Latest Tariff Rate Details (Including Surtaxes & Policy Surcharges)

Applicable Country: United States (US)
Origin: China (CN)
Effective Date: From November 10, 2025 (including subsequent imports)

🎯 1. 3402.31.10.00 —— Alkylbenzene Thickeners (Surfactant Classification)

Item Content
Base Tariff Rate 6.5% (ad valorem)
USITC Surtax +25% (from USITC Footnote under Section 301)
IEEPA Surtax +10% (针对中国/香港产品,自2025年11月10日起)
Total Tariff Rate 41.5%
Tax Calculation CIF Value × 41.5%
De Minimis Exemption Eligible? No (deny_de_minimis)
Legal Basis Path IEEPA:9903.01.25IEEPA:9903.01.24USITC:3402.31.10.00FOOTNOTE:Section 301

📌 Explanation:
- The “USITC Surtax 25%” comes from the “Additional Tariff” under the U.S. Trade Law Section 301;
- The “IEEPA 10%” is the China-specific surtax under the International Emergency Economic Powers Act;
- Total 41.5%, which is a high tariff rate, must be predicted in advance!


🎯 2. 3402.31.90.00 —— Other Surfactants (Functional Chemicals)

Item Content
Base Tariff Rate 3.7% (ad valorem)
USITC Surtax +25%
IEEPA Surtax +10%
Total Tariff Rate 38.7%
Tax Calculation CIF Value × 38.7%
De Minimis Exemption Eligible? ❌ No
Legal Basis Path IEEPA:9901.25IEEPA:9903.01.24USITC:3402.31.90.00FOOTNOTE:Section 301

📌 Note:
- Similar to the previous entry, but with a lower base tariff (3.7% vs 6.5%);
- Applies to functional chemical surfactants that do not fall under the specific sulfonate category.


🎯 3. 3824.40.10.00 —— Chemical Industry Additives (Aromatic Substances)

Item Content
Base Tariff Rate 6.5% (ad valorem)
USITC Surtax +25%
IEEPA Surtax +10%
Total Tariff Rate 41.5%
Tax Calculation CIF Value × 41.5%
De Minimis Exemption Eligible? ❌ No
Legal Basis Path IEEPA:9903.01.25IEEPA:9903.01.24USITC:3824.40.10.00FOOTNOTE:Section 301

📌 Note:
- Classified under chemical additives due to aromatic content;
- Same high tariff structure as surfactant categories.


🎯 4. 3824.99.49.00 —— Other Chemical Products (Hydrocarbon Mixtures)

Item Content
Base Tariff Rate 6.5% (ad valorem)
USITC Surtax +25%
IEEPA Surtax +10%
Total Tariff Rate 41.5%
Tax Calculation CIF Value × 41.5%
De Minimis Exemption Eligible? ❌ No
Legal Basis Path IEEPA:9903.01.25IEEPA:9903.01.24USITC:3824.99.49.00FOOTNOTE:Section 301

📌 Note:
- Applies to petroleum-derived hydrocarbon thickeners;
- This is the most common classification for generic alkylbenzene thickeners not specified as surfactants.


🛠️ Part 4: Customs Clearance Practical Advice (Real-World Pitfall Avoidance Guide)

✅ 1. Preparation Checklist (All Required)

Document Required Description
✅ Product Specification Sheet ✔️ Must include chemical composition, CAS numbers, usage, physical state
✅ Formula/Composition Report ✔️ Critical to prove whether it’s a surfactant or hydrocarbon mixture
✅ Product Photos (with Label) ✔️ Clear display of model, brand, chemical name, and safety warnings
✅ Third-Party Test Report ✔️ SDS (Safety Data Sheet), GHS labeling, MSDS if applicable
✅ Commercial Invoice ✔️ Clearly state “Alkylbenzene Thickening Agent” or “Surfactant Preparation”
✅ Certificate of Origin (CO) ✔️ If not from China, may qualify for preferential rates
✅ Packing List ✔️ Specify bulk vs. packaged, avoid splitting declarations

✅ 2. Declaration Tips (Key Mantras)

🔥 “Clarify Chemistry, Declare Correctly, Avoid 41.5% Penalty!”

Situation Correct Declaration Wrong Practice
Surfactant-based (sulfonates) 3402.31.10.00 Misdeclared as hydrocarbon → 41.5%
Hydrocarbon mixture 3824.99.49.00 Misdeclared as surfactant → 41.5%
Chemical additive (aromatic) 3824.40.10.00 Misdeclared as generic chemical → delays
Multi-purpose thickener Provide formula proof Vague description “Thickener” → Audit risk

✅ 3. Special Case Handling

Situation Recommendation
OEM Custom Thickeners Provide client order + formulation to avoid “generic” classification
Hybrid Products (Surfactant + Hydrocarbon) Declare based on primary function; provide chemical analysis report
Used in Food/Cosmetic Industry Must provide FDA/USDA compliance documents; may require additional approvals
Industrial Oil Additives Ensure SDS matches chemical identity; avoid “grease” or “lubricant” misclassification

🌍 Part 5: Global Market Customs Comparison (2026 Latest)

Country/Region Recommended HS Code Tariff Certification Requirement Notes
🇺🇸 USA 3824.99.49.00 / 3402.31.10.00 38.7%–41.5% (China Origin) SDS, GHS Labeling High surtax due to Section 301
🇨🇳 China 3824.99.49.00 6.5% (Import) CCC (if applicable) No surtax
🇪🇺 EU 3824.99.49.00 / 3402.31.90.00 0%–6.5% REACH, CLP No surtax
🇦🇺 Australia 3824.99.49.00 5% NICNAS/AICIS No surtax
🇯🇵 Japan 3824.99.49.00 0%–5% JIS Standards No surtax

📌 Conclusion:
- The US imposes the highest tariff burden on Chinese-origin alkylbenzene additives;
- EU and Japan are more favorable markets with lower or zero tariffs;
- Diversify supply chain if targeting the US market heavily.


📌 Part 6: Common Errors & Pitfall Guide (Lessons Learned)

Error 1: Declaring a hydrocarbon mixture as “Surfactant” to seek lower base tariff
👉 Consequence: Customs audit → Penalties + Back duties!

Error 2: Using vague terms like “Thickener” without chemical details
👉 Consequence: Clearance delay + Request for additional documentation

Error 3: Not providing SDS or Formula Report
👉 Consequence: Customs cannot verify classification → Goods held or returned

Error 4: Splitting shipments to avoid high tariffs
👉 Consequence: Anti-circumvention investigation + Fines

Correct Practice:

“Alkylbenzene Sulfonate Surfactant, 70% Active, Linear Alkylbenzene, for Industrial Cleaning, CAS No. XXXXX, SDS Attached, GHS Compliant”


🎯 Part 7: Conclusion – Precise Classification Saves Money!

🎯 Remember Mantras:

🔹 “Surfactant vs. Hydrocarbon? Check the Formula!”
🔹 “HS Code Defines Duty, 41.5% vs 38.7% Matters!”
🔹 “Misclassification Costs More Than Correct Declaration!”


📌 Tips:
- If your alkylbenzene additive originates from Vietnam, Thailand, or Malaysia, you may qualify for IEEPA Exemptions, reducing tariffs to 0%–6.5%;
- Apply for Advance Ruling from US Customs (CBP) before shipment to secure classification certainty.


📣 Act Now:

📞 Contact Professional Customs Broker + Provide Chemical Formula + Apply for HS Code Advance Ruling
🚀 Ensure Smooth Clearance, Lower Costs, Higher Profits!


Professional Customs Clearance Starts with Precise Classification!
💼 Every Cent of Cost Deserves Accurate Calculation!

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About HS Code Classification

The Harmonized System (HS) is an internationally standardized nomenclature developed by the World Customs Organization (WCO) to classify traded products. Over 200 countries use the HS system as the basis for customs tariffs, trade statistics, and import/export regulations.

Each HS code follows a hierarchical structure:

  • Chapter (2 digits) — Broad category of goods (e.g., Chapter 84: Machinery and Mechanical Appliances)
  • Heading (4 digits) — More specific grouping within the chapter
  • Subheading (6 digits) — Internationally standardized breakdown, used by all WCO member countries
  • National subdivisions (8-10 digits) — Country-specific extensions for further classification, such as US HTSUS 10-digit codes

Correct HS code classification is essential for smooth customs clearance, accurate duty payment, and compliance with trade regulations. Misclassification can lead to customs delays, overpayment of duties, or penalties.

When importing from CN to US, the applicable tariff rates may include:

  • Most-Favored-Nation (MFN) rate — The standard duty rate applied to WTO members
  • General rate — Applied to countries without trade agreements
  • Trade remedy duties — Additional tariffs such as Section 301 (anti-dumping), Section 232 (national security), or countervailing duties

The information provided on this page is for reference purposes only. For official classification, please consult with your local customs authority or a licensed customs broker.