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Alkylbenzene Surfactant

CN β†’ US
HS Code Tariff Rate Origin Destination Doc
2904105000 39.2% CN US Official Doc
3402319000 38.7% CN US Official Doc
3402311000 41.5% CN US Official Doc
3824992100 35.0% CN US Official Doc
2904103700 40.5% CN US Official Doc

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πŸ§ͺ Alkylbenzene Surfactants (Chemical Industrial Products)


🌐 HS Code Reference & Customs Clearance Guide | 2026 Latest Tariff Analysis | Professional Clearance Strategy
πŸ“Œ I. Product Definition & Classification: What Exactly Is "Alkylbenzene Surfactant"?

Alkylbenzene surfactants are critical ingredients in the chemical industry, primarily used in detergents, cleaning agents, and industrial processing. In international trade, they are categorized based on their chemical structure, specific sulfonated derivatives, and functional application.

Because these products are complex organic compounds, their HS Code classification varies significantly depending on whether they are classified as surface-active agents (Chapter 34) or chemical derivatives/hydrocarbon derivatives (Chapters 29 & 38).

⚠️ Key Classification Distinction:
- If the product is primarily defined by its surface-active properties (e.g., used for wetting, emulsifying), it often falls under Chapter 34.
- If the product is defined by its chemical synthesis process (sulfonation, nitration of hydrocarbons), it may fall under Chapter 29 (Organic Chemicals).
- If the product is a generic chemical preparation not specifically described elsewhere, it may fall under Chapter 38.


πŸ“¦ II. HS Code Classification Details (2026 Latest Tariff Authority Comparison)

HS Code Product Description Applicability Scenario Material Attribute
3402.31.10.00 Alkylbenzene surfactants & linear alkylbenzene sulfonates & their salts High material consistency with linear alkylbenzene sulfonates; considered the same category of chemical substances. Same material attributes as LABS
3402.31.90.00 Other alkylbenzene surfactants & similar surface-active agents Highly consistent core attributes with linear alkylbenzene sulfonates; classified as similar anionic organic surfactants. Anionic organic surfactant
3824.99.21.00 Chemical products & preparations of the chemical or allied industries Alkylbenzene surfactants are organic chemical synthetics, fitting the attribute of chemical preparations. Organic chemical synthetic
2904.10.37.00 Derivatives of hydrocarbons, sulfonated, nitrated or nitrosated Alkylbenzene surfactants are aromatic hydrocarbon derivatives, matching the chemical characteristics of sulfonated/nitrated derivatives. Aromatic hydrocarbon derivative
2904.10.50.00 Other derivatives of hydrocarbons, sulfonated or nitrated Alkylbenzene surfactants are hydrocarbon derivatives matching sulfonated/nitrated material characteristics; classified under other categories. Hydrocarbon derivative

πŸ” Critical Reminder:
- Chapter 34 (3402.31.x) is typically preferred if the product is marketed specifically as a surfactant with defined surface-active functions.
- Chapter 29 (2904.10.x) applies if the customs authority focuses on the chemical structure as a sulfonated hydrocarbon derivative.
- Chapter 38 (3824.99.21) is a fallback for chemical preparations that do not fit the specific definitions of Chapters 29 or 34.


πŸ’° III. 2026 Latest Tariff Rate Details (Including Surtaxes, Policy Add-ons)

βœ… Applicable Country: United States (US)
βœ… Origin: China (CN)
βœ… Effective Date: From November 10, 2025 (including subsequent imports)

🎯 1. 3402.31.10.00 β€”β€” Alkylbenzene Surfactants (High Material Consistency)

Item Content
Base Tariff 6.5% (ad valorem)
Section 301 Surtax +25.0% (From USITC Footnote 9903.88.01)
Section 122 Surtax +10.0% (Specific to Chinese products)
Total Tariff Rate 41.5%
Tax Calculation CIF Value Γ— 41.5%
De Minimis Eligibility ❌ No (deny_de_minimis)
Legal Basis Path USITC:3402.31.10.00 β†’ FOOTNOTE:9903.88.01 β†’ SECTION:122

πŸ“Œ Explanation:
- The 25% surtax is part of the Section 301 tariffs on Chinese goods;
- The 10% surtax is an additional Section 122 tariff for certain chemical/industrial goods from China;
- Total 41.5% is a high tariff burden. Pre-calculation is essential!


🎯 2. 3402.31.90.00 β€”β€” Other Alkylbenzene Surfactants (Anionic Organic Surfactants)

Item Content
Base Tariff 3.7%
Section 301 Surtax +25.0%
Section 122 Surtax +10.0%
Total Tariff Rate 38.7%
Tax Calculation CIF Value Γ— 38.7%
De Minimis Eligibility ❌ No
Legal Basis Path USITC:3402.31.90.00 β†’ FOOTNOTE:9903.88.01 β†’ SECTION:122

πŸ“Œ Note:
- Similar to the previous item, this classifies surfactants with similar anionic organic properties;
- Even if the specific alkyl chain length differs, if the core attribute is the same, this code applies.


🎯 3. 3824.99.21.00 β€”β€” Chemical Preparations (Organic Chemical Synthetics)

Item Content
Base Tariff 0.0%
Section 301 Surtax +25.0%
Section 122 Surtax +10.0%
Total Tariff Rate 35.0%
Tax Calculation CIF Value Γ— 35.0%
De Minimis Eligibility ❌ No
Legal Basis Path USITC:3824.99.21.00 β†’ FOOTNOTE:9903.88.01 β†’ SECTION:122

πŸ“Œ Advantage:
- This code has the lowest total tariff (35.0%) among the options because the base tariff is 0%;
- Suitable if the product is a generic chemical preparation without specific surfactant function claims.


🎯 4. 2904.10.37.00 β€”β€” Aromatic Hydrocarbon Derivatives (Sulfonated/Nitrated)

Item Content
Base Tariff 5.5%
Section 301 Surtax +25.0%
Section 122 Surtax +10.0%
Total Tariff Rate 40.5%
Tax Calculation CIF Value Γ— 40.5%
De Minimis Eligibility ❌ No
Legal Basis Path USITC:2904.10.37.00 β†’ FOOTNOTE:9903.88.01 β†’ SECTION:122

πŸ“Œ Chemical Focus:
- This classification emphasizes the aromatic nature and sulfonation/nitration process;
- Use if the technical data sheet highlights the chemical derivative structure over surfactant function.


🎯 5. 2904.10.50.00 β€”β€” Other Hydrocarbon Derivatives

Item Content
Base Tariff 4.2%
Section 301 Surtax +25.0%
Section 122 Surtax +10.0%
Total Tariff Rate 39.2%
Tax Calculation CIF Value Γ— 39.2%
De Minimis Eligibility ❌ No
Legal Basis Path USITC:2904.10.50.00 β†’ FOOTNOTE:9903.88.01 β†’ SECTION:122

πŸ“Œ Fallback for Chapter 29:
- Applies if the product is a hydrocarbon derivative but doesn't fit the specific sub-headings of 37 or other specific derivatives;
- Total tariff is 39.2%, higher than the 3824 option but lower than 2904.10.37.


πŸ› οΈ IV. Customs Clearance Practical Advice (Real-World Pitfall Guide)

βœ… 1. Required Documentation Checklist (All are Mandatory)

Document Must Provide Description
βœ… Technical Data Sheet (TDS) βœ”οΈ Must specify chemical composition, CAS number, and surfactant type
βœ… Safety Data Sheet (SDS) βœ”οΈ Classify as hazardous or non-hazardous according to GHS standards
βœ… Product Photos (Including Label) βœ”οΈ Clear view of packaging, chemical name, and concentration
βœ… Third-Party Test Report βœ”οΈ COA (Certificate of Analysis) confirming purity and chemical structure
βœ… Commercial Invoice βœ”οΈ Must clearly state "Alkylbenzene Surfactant" or specific chemical name
βœ… Certificate of Origin (CO) βœ”οΈ If from non-China countries, may qualify for reduced tariffs
βœ… Packing List βœ”οΈ Detail net/gross weight, volume, and container type

βœ… 2. Declaration Tips (Key Mantra)

πŸ”₯ "Structure Determines Code, Function Determines Duty! Don't Mix Chapters!"

Scenario Correct Declaration Wrong Practice
Product is a surface-active agent with clear wetting/emulsifying function 3402.31.10.00 or 3402.31.90.00 Misdeclare as chemical raw material β†’ 41.5% or 38.7%
Product is a generic chemical mix without specific surfactant function claims 3824.99.21.00 Misdeclare as surfactant β†’ Higher base tariff
Product is a sulfonated aromatic derivative (chemical focus) 2904.10.37.00 or 2904.10.50.00 Misdeclare as general chemical β†’ 40.5% or 39.2%
Liquid Concentrate Declare as "Chemical Preparation" if concentration is high Declare as "Surfactant" if function is unclear β†’ Risk of reclassification

βœ… 3. Special Case Handling

Scenario Handling Advice
OEM Custom Surfactants Provide client order + formula structure to avoid "generic" classification
High Concentration vs. Diluted Diluted products may still be classified as surfactants if function is retained
Mixed with Other Chemicals If it becomes a complex preparation, lean towards 3824.99.21.00
Hazardous Chemicals If classified as hazardous, additional EPA/CGA regulations apply; ensure SDS is GHS-compliant

🌍 V. Global Main Market Clearance Comparison (2026 Latest)

Country/Region Recommended HS Code Tariff Certification Requirements Notes
πŸ‡ΊπŸ‡Έ USA 3824.99.21.00 35.0% (China) EPA Registration, SDS Highest base tariff for Chapter 29/34; 3824 is cost-effective
πŸ‡¨πŸ‡³ China 3402.31.00.00 6.5% No additional surtax Base tariff only; no Section 301/122
πŸ‡ͺπŸ‡Ί EU 3402.31.00.00 6.5% REACH Registration, CLP No additional surtax; REACH is critical
πŸ‡¦πŸ‡Ί Australia 3402.31.00.00 5.0% AICIS Registration No additional surtax
πŸ‡―πŸ‡΅ Japan 3402.31.00.00 0%~6.5% JIS Certification Variable; check specific chemical laws

πŸ“Œ Conclusion:
- The USA imposes the highest effective tariff due to Section 301 and Section 122 add-ons;
- For the US market, 3824.99.21.00 (35.0%) is the most cost-effective compared to Chapter 34 (38.7%-41.5%) and Chapter 29 (39.2%-40.5%);
- Non-US markets generally apply only the base tariff, so Chapter 34 (3402.31) is standard.


πŸ“Œ VI. Common Errors & Pitfall Guide (Lessons Learned)

❌ Error 1: Declaring a chemical derivative as a generic surfactant without proof of surface-active function
πŸ‘‰ Consequence: Customs may reclassify to 3824 or 2904, leading to tariff disputes or delays.

❌ Error 2: Using "Alkylbenzene" alone in the description without specifying sulfonated/surfactant nature
πŸ‘‰ Consequence: Ambiguity in classification β†’ Risk of 41.5% instead of 35.0%.

❌ Error 3: Ignoring Section 122 and Section 301 applicability
πŸ‘‰ Consequence: Underpayment of duties β†’ Back taxes, fines, and potential seizure.

❌ Error 4: Failing to provide SDS/COA for chemical verification
πŸ‘‰ Consequence: Customs request for additional info β†’ Extended clearance time (7-14 days).

βœ… Correct Practice:

"Linear Alkylbenzene Sulfonate (LABS), Powder, 90% Purity, CAS No. 9004-82-4, For Detergent Manufacturing, Non-Hazardous"


🎯 VII. Conclusion: Precision Classification Saves Money!

🎯 Remember the Mantra:

πŸ”Ή "Function First (3402), Chemistry Next (2904), Preparation Last (3824)!"
πŸ”Ή "US Tariff is High, 3824 is Low! Chapter 34 is Safe, Chapter 29 is Complex!"
πŸ”Ή "HS Code Determines Duty, Declaration Determines Speed! One Wrong Digit, Cost Doubles!"


πŸ“Œ Pro Tip:
If your alkylbenzene surfactant is sourced from Vietnam, Mexico, Thailand, or Malaysia, you may qualify for IEEPA Exemptions, reducing tariffs to 0%~5%;
It is highly recommended to apply for an Advance Ruling before shipment to avoid clearance risks.


πŸ“£ Immediate Action:

πŸ“ž Contact a Professional Customs Broker + Provide Technical Data Sheet + Apply for HS Code Advance Ruling
πŸš€ Let your chemicals clear customs smoothly, export efficiently, and maximize profits!


✨ Professional Clearance Starts with Accurate Classification!
πŸ’Ό Every cent of your cost deserves precise calculation!

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About HS Code Classification

The Harmonized System (HS) is an internationally standardized nomenclature developed by the World Customs Organization (WCO) to classify traded products. Over 200 countries use the HS system as the basis for customs tariffs, trade statistics, and import/export regulations.

Each HS code follows a hierarchical structure:

  • Chapter (2 digits) β€” Broad category of goods (e.g., Chapter 84: Machinery and Mechanical Appliances)
  • Heading (4 digits) β€” More specific grouping within the chapter
  • Subheading (6 digits) β€” Internationally standardized breakdown, used by all WCO member countries
  • National subdivisions (8-10 digits) β€” Country-specific extensions for further classification, such as US HTSUS 10-digit codes

Correct HS code classification is essential for smooth customs clearance, accurate duty payment, and compliance with trade regulations. Misclassification can lead to customs delays, overpayment of duties, or penalties.

When importing from CN to US, the applicable tariff rates may include:

  • Most-Favored-Nation (MFN) rate β€” The standard duty rate applied to WTO members
  • General rate β€” Applied to countries without trade agreements
  • Trade remedy duties β€” Additional tariffs such as Section 301 (anti-dumping), Section 232 (national security), or countervailing duties

The information provided on this page is for reference purposes only. For official classification, please consult with your local customs authority or a licensed customs broker.