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Laboratory Halogenated Hydrocarbon Mixture

CN β†’ US
HS Code Tariff Rate Origin Destination Doc
3814005090 41.0% CN US Official Doc
2903770080 13.7% CN US Official Doc
3814005010 41.0% CN US Official Doc
2903799070 38.7% CN US Official Doc
3824995500 38.7% CN US Official Doc

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πŸ§ͺ Laboratory Halogenated Hydrocarbon Mixture


🌐 HS Code Reference & Customs Clearance Guide | 2026 Latest Tariff Analysis | Professional-Level Clearance Strategy
πŸ“Œ I. Product Definition & Classification: Do You Truly Understand β€œHalogenated Hydrocarbons”?

Laboratory Halogenated Hydrocarbon Mixtures are complex chemical compounds primarily used as solvents, reagents, or intermediate raw materials in analytical chemistry, pharmaceutical synthesis, and industrial cleaning. In international trade, their classification is not straightforward due to the interplay between their chemical nature (halogenated derivatives) and functional purpose (mixtures/solvents).

The core debate lies in distinguishing between: * Chemical Derivatives (Heading 2903): If classified by their specific molecular structure as "halogenated hydrocarbons." * Composite Solvents/Preparations (Heading 3814/3824): If classified by their functional use as "mixed solvents" or "chemical preparations" with specific properties.

⚠️ Critical Distinction Point:
- If the mixture acts primarily as a generic solvent blend or industrial preparation without a single dominant chemical identity β†’ Heading 3814 / 3824
- If the mixture is defined by its status as a halogenated derivative of hydrocarbons under Chapter 29, specifically covering mixtures within that subheading β†’ Heading 2903


πŸ“¦ II. HS Code Classification Details (2026 Latest Tariff Authority Comparison)

HS Code Product Description Application Scenario Classification Logic
3814.00.50.90 Other organic compound mixtures (Special Halogenated Hydrocarbon Mixture) Composite solvents, industrial chemical preparations βœ… Classified as "Organic Composite Solvent" under general heading 3814
2903.77.00.80 Halogenated derivatives of hydrocarbons, other Specific halogenated hydrocarbon derivatives, mixtures covered under "other" βœ… Classified as "Halogenated Derivative" under Chapter 29
3814.00.50.10 Organic solvents (Specifically similar to Methyl Chloroform or Carbon Tetrachloride) Solvents with chemical attributes consistent with known chlorinated solvents βœ… Classified based on chemical property consistency with known solvents
2903.79.90.70 Halogenated derivatives, containing 2+ different halogens Mixtures with multiple different halogen types (e.g., Cl, Br, F together) βœ… Classified by multi-halogen composition logic under Chapter 29
3824.99.55.00 Other chemical products not elsewhere specified (Halogenated Hydrocarbon Material) Other specific subclasses with halogenated hydrocarbon attributes βœ… Classified as "Other Specific Subclass" under general chemical preparations

πŸ” Key Reminder:
- Heading 3814/3824 focuses on the functional use (solvent/preparation). These codes typically attract higher duties due to "Section 301" and "Section 122" penalties. - Heading 2903 focuses on the chemical structure. Even though it is a mixture, if it falls under the specific subheadings for halogenated derivatives, it may have a lower base duty, but is still subject to trade war tariffs. - Note on "Mixture": Chapter 29 Note 1 allows for mixtures of products of the same heading. Thus, a mixture of halogenated hydrocarbons can still fall under 2903 if it meets the criteria.


πŸ’° III. 2026 Latest Tariff Rate Breakdown (Including Additional Taxes & Policy Surcharges)

βœ… Applicable Country: United States (US)
βœ… Origin: China (CN)
βœ… Effective Date: From November 10, 2025 (Including subsequent imports)

🎯 1. 3814.00.50.90 β€”β€” Other Organic Compound Mixtures (Composite Solvents)

Item Content
Base Duty Rate 6.0% (ad valorem)
Section 301 Additional Duty +25.0%
Section 122 Duty +10.0%
Total Duty Rate 41.0%
Tax Calculation CIF Value Γ— 41.0%
De Minimis Exemption ❌ Not Available (denied_de_minimis)
Legal Basis Path USITC:3814.00.50.90 β†’ Footnote: Section 301 β†’ Section 122 Authority

πŸ“Œ Explanation:
- Base 6%: Standard MFN rate for mixed solvents. - +25%: From USITC Footnote under Section 301 (Trade War). - +10%: From Section 122 (National Security/Trade Balance). - Total 41%: A very high tax burden. This classification is risky for cost-sensitive imports.


🎯 2. 2903.77.00.80 β€”β€” Halogenated Derivatives of Hydrocarbons (Other)

Item Content
Base Duty Rate 3.7% (ad valorem)
Section 301 Additional Duty 0.0%
Section 122 Duty +10.0%
Total Duty Rate 13.7%
Tax Calculation CIF Value Γ— 13.7%
De Minimis Exemption ❌ Not Available (denied_de_minimis)
Legal Basis Path USITC:2903.77.00.80 β†’ Section 122 Authority

πŸ“Œ Note:
- Lowest Total Duty: Among all options, this has the lowest total rate (13.7%). - Why 0% Section 301? Certain specific chemical derivatives under 2903.77 may be excluded from the Section 301 list or have different footnote rules. However, this is highly dependent on the exact chemical composition and USITC updates. - Strategy: If your mixture strictly qualifies as a "halogenated derivative" under 2903.77, this is the most cost-effective option.


🎯 3. 3814.00.50.10 β€”β€” Organic Solvents (Specific to Methyl Chloroform/CCl4 attributes)

Item Content
Base Duty Rate 6.0% (ad valorem)
Section 301 Additional Duty +25.0%
Section 122 Duty +10.0%
Total Duty Rate 41.0%
Tax Calculation CIF Value Γ— 41.0%
De Minimis Exemption ❌ Not Available (denied_de_minimis)
Legal Basis Path USITC:3814.00.50.10 β†’ Footnote: Section 301 β†’ Section 122 Authority

πŸ“Œ Warning:
- Even if the chemical properties match Methyl Chloroform, if it is classified as a "mixture/solvent preparation" (3814), it attracts the same high tax (41%) as other composite solvents. - Do not assume "chemical similarity" automatically leads to lower Chapter 29 duties if the product is defined as a "mixture/preparation."


🎯 4. 2903.79.90.70 β€”β€” Halogenated Derivatives (2+ Halogens)

Item Content
Base Duty Rate 3.7% (ad valorem)
Section 301 Additional Duty +25.0%
Section 122 Duty +10.0%
Total Duty Rate 38.7%
Tax Calculation CIF Value Γ— 38.7%
De Minimis Exemption ❌ Not Available (denied_de_minimis)
Legal Basis Path USITC:2903.79.90.70 β†’ Footnote: Section 301 β†’ Section 122 Authority

πŸ“Œ Analysis:
- If the mixture contains two or more different halogens (e.g., Chlorine and Bromine), it may fall under 2903.79. - However, unlike 2903.77, this subheading is subject to the 25% Section 301 tariff. - Total 38.7% is significantly higher than the 13.7% option above.


🎯 5. 3824.99.55.00 β€”β€” Other Chemical Products (Halogenated Hydrocarbon Material)

Item Content
Base Duty Rate 3.7% (ad valorem)
Section 301 Additional Duty +25.0%
Section 122 Duty +10.0%
Total Duty Rate 38.7%
Tax Calculation CIF Value Γ— 38.7%
De Minimis Exemption ❌ Not Available (denied_de_minimis)
Legal Basis Path USITC:3824.99.55.00 β†’ Footnote: Section 301 β†’ Section 122 Authority

πŸ“Œ Note:
- This is a "catch-all" for chemical products not elsewhere specified. - Like the multi-halogen derivative, it attracts the full 25% Section 301 tariff. - Use only if the product cannot be classified under 3814 or 2903 specifically.


πŸ› οΈ IV. Customs Clearance Practical Advice (Battle-Tested Pitfall Guide)

βœ… 1. Preparation Checklist (All Documents Mandatory)

Document Mandatory? Explanation
βœ… Product Specification Sheet βœ”οΈ Must detail chemical composition, percentage of each halogen, and primary use.
βœ… Safety Data Sheet (SDS) βœ”οΈ Critical for identifying HazMat class and verifying chemical nature.
βœ… Product Photos (Labeled) βœ”οΈ Clear label showing "Mixture," chemical names, and hazard symbols.
βœ… Certificate of Analysis (COA) βœ”οΈ To prove it is indeed a mixture and not a pure compound, or vice versa.
βœ… Commercial Invoice βœ”οΈ Clearly state "Halogenated Hydrocarbon Mixture" and HS Code.
βœ… Origin Certificate (CO) βœ”οΈ Essential for verifying Chinese origin to apply correct surtaxes.
βœ… Packaging List βœ”οΈ Show packaging type (drum, IBC, etc.) for HazMat inspection.

βœ… 2. Declaration Tips (Key Mantra)

πŸ”₯ β€œChemistry First, Function Second, List Components, Avoid Confusion!”

Scenario Correct Declaration Wrong Practice
Mixture acts as solvent 2903.77.00.80 (If eligible) Declare as 3814 β†’ 41% Tax
Mixture with Cl, Br, F 2903.79.90.70 Declare as 3814 β†’ 41% Tax
Generic Chlorinated Solvent Blend 3814.00.50.90 Under-declare value
Strategic Choice Aim for 2903.77.00.80 If composition allows, choose 13.7% tax

βœ… 3. Special Situation Handling

Situation Handling Advice
OEM Custom Mix Provide exact formulation (percentage breakdown) to customs broker. Avoid vague terms like "Industrial Solvent."
Contains Restricted Chemicals Check if any component is on the EPA TSCA Inventory or restricted list. Non-compliance leads to seizure.
High Purity vs. Mixture If it’s a pure halogenated hydrocarbon, it might fall under a different 2903 subheading (e.g., 2903.14 for CFCs, etc.). Do not use 2903.77 for pure compounds.
HazMat Shipping Halogenated hydrocarbons are often flammable or toxic. Ensure correct UN Number and Class 3/6.1/8 classification.

🌍 V. Global Market Clearance Comparison (2026 Latest)

Country/Region Recommended HS Code Duty Rate (China Origin) Certification Requirements Notes
πŸ‡ΊπŸ‡Έ USA 2903.77.00.80 13.7% (Best Case) TSCA Compliance Avoid 3814 if possible (41%).
πŸ‡ͺπŸ‡Ί EU 2903.77.00.00 ~6.5% REACH Registration High environmental scrutiny.
πŸ‡¨πŸ‡³ China 2903.77.00.80 ~3.7% MSDS, Labeling No additional trade war tariffs.
πŸ‡―πŸ‡΅ Japan 2903.77.00.00 ~5.5% JIS, PRTR Report Strict chemical notification laws.

πŸ“Œ Conclusion:
- The US is the most challenging market due to Section 301 and Section 122 tariffs. - Strategic Goal: Try to classify under 2903.77.00.80 to achieve 13.7% instead of 41%. This requires robust chemical documentation proving it fits the "halogenated derivative" definition under Chapter 29.


πŸ“Œ VI. Common Errors & Pitfall Guide (Lessons Learned)

❌ Error 1: Declaring as 3814.00.50.90 (Solvent) without proving it doesn't fit 2903
πŸ‘‰ Consequence: Pay 41% tax instead of 13.7%. Overpayment of nearly 30%!

❌ Error 2: Vague description "Chemical Mixture"
πŸ‘‰ Consequence: Customs may downgrade to the highest duty code or hold shipment for classification review. Delay + Storage Fees.

❌ Error 3: Ignoring Section 122 (10% tax)
πŸ‘‰ Consequence: All 5 HS Codes above include the 10% Section 122 duty. Failing to budget for this leads to cash flow issues.

βœ… Correct Approach:

"Laboratory Grade Halogenated Hydrocarbon Mixture, CAS No. XXXX-XX-X, Containing Chloro- and Bromo- derivatives, for Analytical Use Only. HS Code: 2903.77.00.80."


🎯 VII. Conclusion: Precise Classification Saves Costs!

🎯 Remember the Mantra:

πŸ”Ή "Chapter 29 is Cheaper, Chapter 38 is Expensive."
πŸ”Ή "13.7% vs 41%: The difference is in the chemical definition."
πŸ”Ή "Section 122 applies to ALL: Add 10% to every calculation!"


πŸ“Œ Pro Tip:

If your mixture can be scientifically proven to be a "Halogenated Derivative" under 2903.77, file a Pre-Ruling Application with US Customs and Border Protection (CBP).
πŸš€ Result: Potential tax savings of 27.3% (41% - 13.7%) on the CIF value.
πŸ“ž Action: Contact a licensed customs broker immediately with your COA (Certificate of Analysis) and SDS to validate the 2903.77 classification before shipment.


✨ Professional Clearance Starts with Accurate Classification!
πŸ’Ό Every percent of duty saved is pure profit!

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About HS Code Classification

The Harmonized System (HS) is an internationally standardized nomenclature developed by the World Customs Organization (WCO) to classify traded products. Over 200 countries use the HS system as the basis for customs tariffs, trade statistics, and import/export regulations.

Each HS code follows a hierarchical structure:

  • Chapter (2 digits) β€” Broad category of goods (e.g., Chapter 84: Machinery and Mechanical Appliances)
  • Heading (4 digits) β€” More specific grouping within the chapter
  • Subheading (6 digits) β€” Internationally standardized breakdown, used by all WCO member countries
  • National subdivisions (8-10 digits) β€” Country-specific extensions for further classification, such as US HTSUS 10-digit codes

Correct HS code classification is essential for smooth customs clearance, accurate duty payment, and compliance with trade regulations. Misclassification can lead to customs delays, overpayment of duties, or penalties.

When importing from CN to US, the applicable tariff rates may include:

  • Most-Favored-Nation (MFN) rate β€” The standard duty rate applied to WTO members
  • General rate β€” Applied to countries without trade agreements
  • Trade remedy duties β€” Additional tariffs such as Section 301 (anti-dumping), Section 232 (national security), or countervailing duties

The information provided on this page is for reference purposes only. For official classification, please consult with your local customs authority or a licensed customs broker.