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低分子量聚醚

CN → US
HS Code Tariff Rate Origin Destination Doc
3907210000 41.5% CN US Official Doc
3403915000 41.5% CN US Official Doc
3402422010 39.0% CN US Official Doc

AI Analysis

🧪 Low Molecular Weight Polyethers (LMWEs)


🌐 HS Code Reference & Customs Clearance Guide | 2026 Latest Tariff Analysis | Professional Entry Strategy
📌 Part 1: Product Definition & Classification: Do You Really Understand "Low Molecular Weight Polyethers"?

Low Molecular Weight Polyethers (LMWEs) are oligomeric ethers, typically formed by the polymerization of ethylene oxide, propylene oxide, or mixed oxides. In international trade, their classification is critical because they can serve as raw materials for resins, surfactants, or chemical agents, depending on their molecular weight, end groups, and application.

Key Classification Divergence: 1. As Polymers (Plastics/Resins): If treated primarily as chemical intermediates for further polymerization (e.g., for polystyrene or epoxy resins), they fall under Chapter 39. 2. As Surface Active Agents: If formulated for wetting, emulsifying, or dispersing properties, they fall under Chapter 34 (Surface Active Agents). 3. As Chemical Mixtures: If used as lubricating grease bases or other chemical preparations, they may fall under Chapter 34 or 3403.

⚠️ Critical Distinction:
- If the primary function is polymerization precursor → Classify under 3907 (Polyethers).
- If the primary function is surfactant/emulsifier → Classify under 3402 (Surface Active Agents).
- If mixed with other chemical agents for specific industrial use → Classify under 3403/3402.


📦 Part 2: HS Code Classification Details (2026 Latest Tariff Authority Match)

Based on the provided data, here are the five valid HS Code options for "Low Molecular Weight Polyethers" with corresponding tax rates and legal justifications.

HS Code Product Description Application/Logic Total Tax Rate
3907.21.00.00 Polyethers, low molecular weight, in primary forms Classified as "Other Polyethers" in primary shape; matches raw material nature for resin production. 41.5%
3402.42.20.10 Surface Active Agents, organic, non-ionic Classified as non-ionic organic surface active agents; material and form match surfactant properties. 39.0%
3403.91.50.00 Chemical Preparations, lubricating greases & others Classified as a chemical preparation; no material attribute conflict; often used as grease base or additive. 41.5%
3903.11.00.00 Polystyrene, in primary forms Note: Data summary mentions "Low molecular weight polystyrene resin". Classified as polystyrene polymer in primary shape. 41.5%
3903.19.00.00 Polystyrene, other Classified as "Other" polystyrene polymers; matches definition if not strictly "primary form" or specific subtype. 41.5%

🔍 Important Note on 3903.xxxx Codes:
While the product name is "Polyether," the provided data maps 3903.11 and 3903.19 to "Low Molecular Weight Polystyrene Resin." This suggests a potential material confusion or specific derivative (e.g., etherified polystyrene) in the source data.
- If the product is pure Polyether → Use 3907 or 3402.
- If the product is Polystyrene-based → Use 3903.
- Clarification is mandatory to avoid misclassification penalties.


💰 Part 3: 2026 Latest Tariff Rate Breakdown (Including Surtaxes & Policy Add-ons)

Applicable Country: United States (US)
Origin: China (CN)
Effective Date: November 10, 2025 (and onwards)

🎯 1. 3907.21.00.00 —— Polyethers, Low Molecular Weight (Primary Form)

Item Content
Base Duty Rate 6.5%
Section 301 Surtax +25.0%
Section 122 Tariff +10.0% (New China-specific levy)
Total Tax Rate 41.5%
Tax Calculation CIF Value × 41.5%
De Minimis Eligibility Not Eligible (High tariff codes excluded)
Legal Basis Path USITC:3907.21.00.00SECTION301:9903.03.01SECTION122:9903.04.01

📌 Explanation:
- Base 6.5%: Standard MFN rate for polyethers.
- 301 Surtax 25%: Applies to Chinese-origin chemicals/polyers under Section 301.
- Section 122 10%: New additional levy on specific Chinese chemical products.
- Total 41.5%: High cost entry. Must verify if the product qualifies for any exclusion (Exclusion List not mentioned in data, so assume applicable).


🎯 2. 3402.42.20.10 —— Non-Ionic Organic Surface Active Agents

Item Content
Base Duty Rate 4.0%
Section 301 Surtax +25.0%
Section 122 Tariff +10.0%
Total Tax Rate 39.0%
Tax Calculation CIF Value × 39.0%
De Minimis Eligibility Not Eligible
Legal Basis Path USITC:3402.42.20.10SECTION301:9903.03.01SECTION122:9903.04.01

📌 Explanation:
- Base 4.0%: Lower base rate for surface active agents.
- Total 39.0%: Still high, but 2.5% cheaper than 3907 classification.
- Strategic Tip: If the polyether functions clearly as a surfactant, this code offers the lowest total tax burden among all options.


🎯 3. 3403.91.50.00 —— Chemical Preparations (Other)

Item Content
Base Duty Rate 6.5%
Section 301 Surtax +25.0%
Section 122 Tariff +10.0%
Total Tax Rate 41.5%
Tax Calculation CIF Value × 41.5%
De Minimis Eligibility Not Eligible
Legal Basis Path USITC:3403.91.50.00SECTION301:9903.03.01SECTION122:9903.04.01

📌 Explanation:
- Used when the product is a mixture or preparation not strictly a pure polymer or surfactant.
- Same tax burden as 3907.21.00.00. Use only if 3907 and 3402 are technically incorrect.


🎯 4. 3903.11.00.00 —— Polystyrene in Primary Forms

Item Content
Base Duty Rate 6.5%
Section 301 Surtax +25.0%
Section 122 Tariff +10.0%
Total Tax Rate 41.5%
Tax Calculation CIF Value × 41.5%
De Minimis Eligibility Not Eligible
Legal Basis Path USITC:3903.11.00.00SECTION301:9903.03.01SECTION122:9903.04.01

📌 Explanation:
- ⚠️ Risk Alert: This code is for Polystyrene, not Polyether.
- Only use if the product is Etherified Polystyrene or a Polystyrene Resin.
- Misclassification here is high-risk because the chemical nature differs significantly from standard Polyethers.


🎯 5. 3903.19.00.00 —— Other Polystyrene

Item Content
Base Duty Rate 6.5%
Section 301 Surtax +25.0%
Section 122 Tariff +10.0%
Total Tax Rate 41.5%
Tax Calculation CIF Value × 41.5%
De Minimis Eligibility Not Eligible
Legal Basis Path USITC:3903.19.00.00SECTION301:9903.03.01SECTION122:9903.04.01

📌 Explanation:
- Same risk as 3903.11. Use only for non-primary form or specialty Polystyrene.
- Not recommended for standard Low Molecular Weight Polyethers.


🛠️ Part 4: Customs Clearance Practical Advice (Battle-Tested Pitfall Avoidance)

✅ 1. Required Documentation Checklist (Non-negotiable)

Document Must Provide Explanation
Technical Data Sheet (TDS) ✔️ Must specify Molecular Weight, EO/PO ratio, End Groups.
COA (Certificate of Analysis) ✔️ Confirms purity and chemical structure.
Product Photo (Label) ✔️ Clear view of chemical name, CAS number, and hazard symbols.
Usage Statement ✔️ "Used as surfactant" vs. "Used as polymer precursor" determines HS Code.
Bill of Lading & Invoice ✔️ Must match HS Code description exactly.
Original Certificate of Origin ✔️ Required for Section 301/122 tariff verification.

✅ 2. Classification Strategy (Key Mantra)

🔥 "Function Dictates HS Code: Surfactant = 3402, Polymer = 3907, Mixed = 3403"

Scenario Correct HS Code Incorrect Code Consequence
Pure LMWE for making resins 3907.21.00.00 (41.5%) 3402 No tax savings, but wrong classification risk.
LMWE used as emulsifier/surfactant 3402.42.20.10 (39.0%) 3907 Saves 2.5% tax if functionally accurate.
LMWE mixed with grease/oil 3403.91.50.00 (41.5%) 3907 Avoids misclassification of mixture as pure polymer.
Polystyrene Resin (Not Polyether) 3903.11.00.00 (41.5%) 3907 High Risk: Chemical mismatch → Seizure/Fine.

✅ 3. Special Considerations

Situation Handling Advice
CAS Number Mismatch Ensure the CAS number on the invoice matches the HS Code description. 3907 and 3903 have different CAS ranges.
"Low Molecular Weight" Definition Provide molecular weight (e.g., < 10,000 g/mol) in the declaration to support 3907.21 vs. 3907.99.
Section 122 Tariff This 10% tax is new and strict. Even if you have a 301 exclusion, Section 122 may not be excluded. Check latest USTR guidance.
De Minimis (800 USD) Not Available. These codes are explicitly excluded from Section 321 de minimis treatment. All shipments are subject to duty.

🌍 Part 5: Global Market Comparison (2026 Latest)

Country/Region Recommended HS Code Tariff (China Origin) Key Certifications Notes
🇺🇸 USA 3907.21.00.00 / 3402.42.20.10 39.0% - 41.5% No specific FDA/UL needed for industrial grade Section 301 + 122 Apply. High cost.
🇨🇳 China 3907.21.00.00 6.5% No additional surtaxes Domestic trade benefits from lower base rates.
🇪🇺 EU 3907.21.00 6.5% REACH Registration No Section 301/122 equivalents.
🇬🇧 UK 3907.21.00 6.5% UK REACH Post-Brexit alignment with EU tariffs.
🇯🇵 Japan 3907.21.00 5.0% FSC (if applicable) Generally lower duty rates.

📌 Conclusion:
- USA is the most expensive market due to Section 301 (25%) + Section 122 (10%).
- 3402.42.20.10 offers the lowest duty (39.0%) if the product functions as a surfactant.
- 3903 codes are high-risk if the product is not Polystyrene.


📌 Part 6: Common Errors & Pitfall Guide (Lessons from the Field)

Mistake 1: Classifying all Polyethers under 3907 without considering surfactant function.
👉 Result: Overpaying 2.5% tax unnecessarily.
👉 Fix: Check if the product is sold as a "Surfactant" or "Wetting Agent."

Mistake 2: Confusing "Polyether" with "Polystyrene" (3903).
👉 Result: Customs rejection, fines, and delayed shipment due to chemical mismatch.
👉 Fix: Verify the chemical structure. Polyethers contain ether linkages (-O-); Polystyrene contains phenyl groups.

Mistake 3: Assuming De Minimis (800 USD) applies.
👉 Result: Shipment held at border, duties + storage fees incurred.
👉 Fix: Declare all shipments > $800 properly with full HS Code and duty payment.

Mistake 4: Ignoring Section 122 Tariff.
👉 Result: Underpayment of 10% tax.
👉 Fix: Ensure 10% is included in landed cost calculations.

Correct Declaration Example:

"Low Molecular Weight Polyether, Non-Ionic Surfactant, MW 2000, EO/PO Ratio 3:1, CAS 9003-11-6, Used for Emulsification in Coatings."
HS Code: 3402.42.20.10Tax: 39.0%


🎯 Part 7: Conclusion: Precision Classification Saves Money!

🎯 Remember the Mantra:

🔹 "Surfactant = 3402 (39%), Polymer = 3907 (41.5%), Polystyrene = 3903 (41.5%)"
🔹 "Check Function, Not Just Name. Section 122 Adds 10% Always."
🔹 "De Minimis is Dead for These Codes. Plan for Full Duty."


📌 Pro Tip:
- If your product can be argued as a Surfactant, use 3402.42.20.10 to save 2.5% on the CIF value.
- If it is a Pure Polymer, use 3907.21.00.00.
- Never use 3903 unless it is truly Polystyrene.


📣 Immediate Action:

📞 Contact a licensed customs broker for a Pre-Ruling if the product has mixed functionality.
🚀 Accurate Classification = Lower Costs + Smoother Clearance!


Professional Clearance Starts with Accurate Classification!
💼 Every Percent of Duty Matters!

Customer Reviews

About HS Code Classification

The Harmonized System (HS) is an internationally standardized nomenclature developed by the World Customs Organization (WCO) to classify traded products. Over 200 countries use the HS system as the basis for customs tariffs, trade statistics, and import/export regulations.

Each HS code follows a hierarchical structure:

  • Chapter (2 digits) — Broad category of goods (e.g., Chapter 84: Machinery and Mechanical Appliances)
  • Heading (4 digits) — More specific grouping within the chapter
  • Subheading (6 digits) — Internationally standardized breakdown, used by all WCO member countries
  • National subdivisions (8-10 digits) — Country-specific extensions for further classification, such as US HTSUS 10-digit codes

Correct HS code classification is essential for smooth customs clearance, accurate duty payment, and compliance with trade regulations. Misclassification can lead to customs delays, overpayment of duties, or penalties.

When importing from CN to US, the applicable tariff rates may include:

  • Most-Favored-Nation (MFN) rate — The standard duty rate applied to WTO members
  • General rate — Applied to countries without trade agreements
  • Trade remedy duties — Additional tariffs such as Section 301 (anti-dumping), Section 232 (national security), or countervailing duties

The information provided on this page is for reference purposes only. For official classification, please consult with your local customs authority or a licensed customs broker.